7- Magnetomechanical Response in Polymer Ferrogels.


Advisor: M. E. McHenry, MSE.

Ferrogels are magnetic shape memory materials studied for biomedical applications with Tom Gilbert of the McGowan Tissue Engineering Center. They use magnetic nanoparticle (MNP) chaining in a polymer matrix in response to an applied field to change their mechanical state. The mechanical or thermal response of a MNP-reinforced polymer composites can be tailored by applied DC and AC magnetic fields.  FeCo particles will be modified with surfactants that bind to their thin oxide layer. The mechanical response of magnetoelastic polymer composites will be tuned by control of the matrix crosslink density in collaboration with Michael Bockstaller. Hydrogels will be chosen based on demonstrated shape-changes in low-modulus gels and for tissue engineering applications.  We will investigate FeCo nanorods synthesized by electroless deposition on carbon nanotube templates as provided by Prof. Kalu of Florida A&M University as part of the PREM program.  We will also investigated thermally oxidized FeCo MNPs produced by plasma torch synthesis at CMU.  We will collaborate with investigators at NIST to investigate MNP chaining by small angle neutron scattering (SANS).  This will involve a trip to the NIST reactor in the summer.  Materials will be investigated for their RF heating response for assessing their viability in thermoablative cancer therapies.

 

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